References

1. Jun Xu, Ling-Ying Zhu, Hong Shen, Hong-Mei Zhang, Xiao-Bin Jia, Ru Yan, Song- Lin Li, Hong-Xi Xu. A critical view on spike recovery for accuracy evaluation of analytical method for medicinal herbs // Journal of Pharmaceutical and Biomedical Analysis. 2012. V. 62. P. 210–215. https://doi.org/10.1016/j.jpba.2011.12.034.
2. Diksha Thakur, Neeti Prakash Dubey, Rajvinder Singh. A review on spike and recovery method in analytical method development and validation // Critical Reviews in Analytical Chemistry. 2024. V. 54. № 7. P. 2053–2071. https://doi.org/10.1080/10408347.2022.2152275.
3. Rhijn J.A. van, Tuinstra L.G.M.Th., Traag W.A. Use of spiked samples for the determination of veterinary drug residues in animal tissues by liquid chromatography and gas chromatography-mass spectrometry // Journal of Chromatography A. 1993. V. 624. № 1–2. P. 389–397.
4. Wise S.A., Schantz M.M., Benner Jr. B.A., Parris R.M., Rebbert R.E., Sander L.C., Koster B.J., Chesler S.N., May W.E. Standard reference materials for the determination of polycyclic aromatic hydrocarbons in environmental samples — current activities // Fresenius’ Journal of Analytical Chemistry. 1993. V. 345. P. 325–329. https://doi.org/10.1007/BF00322623.
5. Bogialli S., Di Corcia A. Recent applications of liquid chromatography — mass spectrometry to residue analysis of antimicrobials in food of animal origin // Analytical and Bioanalytical Chemistry. 2009. V. 395. № 4. P. 947–966. https://doi.org/10.1007/s00216-009-2930-6.
6. Mikheeva A.Yu., Krylov A.I. Peculiarities of sample preparation for detrmination of organic toxicants by chromatography / mass spectrometry and isotope dilution method // Measurements in the Modern World — 2015. Collection of Scientific Papers of the 5th All-Russian Scientific and Practical Conference. June 2–4, 2015. St. Petersburg: Polytechnic University Publishing House; 2015. P. 155–161. (In Russ.)
7. Maistrenko V.N., Klyuev N.A. Ecological and Analytical Monitoring of Persistent Organic Pollutants: a textbook for university students studying in the specialty 011000 — Chemistry. 2nd ed. Moscow: BINOM, Laboratoriya znaniy; 2012. 323 p. (In Russ.)
8. Budko A.G. Certified reference material for the composition of phthalates in a polymer matrix based on polyvinyl chloride. Measurement Standards. Reference Materials. 2023; 19 (5): 83–94. EDN: CWVJTT. https://doi.org/10.20915/2077-1177-2023-19-5-83-94.
9. Budko A.G. Metrological support for measurements of the content of priority xenobiotics (phthalates) in natural and industrial facilities: dissertation … of the Candidate of Technical Sciences / FSUE “D.I. Mendeleev All-Russian Institute for Metrology”. St. Petersburg; 2024. 165 p. (In Russ.)
10. Krylov A.I., Budko A.G., Mikheeva A.Y., Tkachenko I.Y., Nezhikhovskiy G.R. Reference method for measuring the content of phthalates in polymer matrices: analytical and metrological approaches. Measurement Techniques. 2022; 10: 64–72. EDN: ZPXIQS. (In Russ.) https://doi.org/10.32446/0368-1025it.2022-10-64-72.
11. Shao Mingwu, Weihua Wang, Masahiko Numata et al. Final report for CCQM-K133: Low-polarity analytes in plastics-phthalate esters in polyvinyl chloride (PVC) // Metrologia. 2025. V. 62. № 1А. 08018. https://doi.org/10.1088/0026-1394/62/1A/08018.
12. Persistent Organic Pollutants (POPS) in the Russian Arctic // Russian Federation — Support for the National Action Plan for the Protection of the Arctic Marine Environment (NAP-Arctic Project) / Global Environment Facility, United Nations Environment Programme; comp. S.B. Tambiev. Moscow: Nauchnyi mir; 2011. P. 568–618. URL: https://archive.iwlearn.org/npa-arctic.iwlearn.org/Documents/da_full/section_4. 3.4.pdf. (In Russ.)
13. Della W.M. Sin, Hongmei Li, Wong S.K., Lo M.F., Wong Y.L., Wong Y.C., Mok C.S. Final report on mid-polarity analytes in food matrix: mid-polarity pesticides in tea // Metrologia. 2015. V. 52. № 1А. 08007. https://doi.org/10.1088/0026-1394/52/1A/08007.
14. The Effects of Herbicides in South Vietnam. Part A. Summary and Conclusions. Washington, D.C.: National Academy of Sciences; 1974. 409 p. URL: https://www.nal.usda.gov/exhibits/speccoll/files/original/a60451fccdcede2554597d92fb5961b5.pdf.
15. Ambient Water Quality Criteria 2,3,7,8-Tetrachlorodibenzo-p-dioxin: EPA-400/5- 84-007 / United States Environmental Protection Agency. Washington, D.C.: Office of Water Regulations and Standards; 1984. 296 p. URL: https://www.epa.gov/sites/de fault/files/2019-02/documents/ambient-wqc-2378tetrachlorodibenzo-1984.pdf.
16. Fedorov L.A. Dioxins as a ecological danger: retrospective and perspective. Moscow: Nauka; 1993. 266 p. (In Russ.)
17. Pozdnyakov S.P., Rumak V.S., Sofronov G.A., Umnova N.V. Dioxins and Human Health: The Scientific Basis for Detecting Dioxin Pathology. St. Petersburg: Nauka; 2006. 274 p. (In Russ.)
18. Budko A.G., Mikheeva A.Y., Krylov A.I. Metrological assurance of dioxin measurements. A certified reference material for measuring the dioxin mass fraction in animal fat. Measurement Standards. Reference Materials. 2018; 14 (3–4): 17–32. EDN: ZBUOUH. https://doi.org/10.20915/2077-1177-2018-14-3-4-17-32.
19. Krylov A.I., Mikheeva A.Y., Budko A.G. Application of gas chromatography with tandem mass spectrometry for certification of the reference material of “dioxins” in animal fat. Measurement Standards. Reference Materials. 2020; 16 (2): 31–40. EDN: UPGXVU. https://doi.org/10.20915/2687-0886-2020-16-2-31-40.

For citation

Krylov A.I., Mikheeva A.Yu., Budko A.G. Features of developing certified reference materials for organic components in matrixes. Almanac of Modern Metrology. 2026; 46 (2): 28–46.

Financing

This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.

Contribution of the authors

A.I. Krylov: overall supervision, research initiation, conceptualization, and methodology design. A.Yu. Mikheeva: literature analysis, experimental design, critical analysis of experimental data, manuscript editing. A.G. Budko: literature collection, experimental data acquisition and analysis, reference material production, preparation of documentation for reference material development and testing, preparation of the original draft of the manuscript.

Conflict of interest

The authors declare no conflict of interest.

About the Authors